After picking up the silver key, quickly position Lara in the far corner of the alcove on the right (at the spot marked with an X in the screenshot above), facing out into the room. Pierre will approach from the other side of the room (along the path marked with the arrow), and she'll remain under cover until he's right in front of her. As soon as he steps into view, blast him twice with the shotgun and he'll run off.
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